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Recovery of indium-tin-oxide/silicon heterojunction solar cells by thermal annealing

机译:通过热退火回收氧化铟锡/硅异质结太阳能电池

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摘要

The emitter of silicon heterojunction solar cells consists of very thin hydrogenated amorphous silicon layers deposited at low\udtemperature. The high sheet resistance of this type of emitter requires a transparent conductive oxide layer, which also acts as\udan effective antireflection coating. The deposition of this front electrode, typically by Sputtering, involves a relatively high energy ion bombardment at the surface that could degrade the emitter quality. The work function of the transparent conductive oxide layer could also significantly modify the band structure at the emitter. In this work, we study the particular case of p-type crystalline silicon substrates with a stack of n-doped and intrinsic amorphous silicon layers deposited by Plasma-Enhanced Chemical Vapor Deposition. The front electrode was an indium-tin-oxide layer deposited by Sputtering. The Quasi-Steady-State Photoconductance technique has been used to characterize the emitter quality by measuring the effective lifetime and the\udimplicit open-circuit voltage. These measurements confirmed a strong degradation of the heterojunction after depositing the\udindium-tin-oxide layer. However, it is also shown that the initial degradation could be completely recovered by an adequate\udthermal treatment. In this sense, annealing times from 10 to 90 minutes at temperatures ranging from 100 to 160 ºC have been\udstudied, both in vacuum and inside an oven.
机译:硅异质结太阳能电池的发射极由在低温下沉积的非常薄的氢化非晶硅层组成。这种类型的发射器的高薄层电阻需要透明的导电氧化物层,该氧化物层还可以用作\ udan有效的抗反射涂层。通常通过溅射沉积该前电极,会在表面上产生较高的能量离子轰击,这可能会降低发射极的质量。透明导电氧化物层的功函数还可以显着改变发射极处的能带结构。在这项工作中,我们研究了通过等离子体增强化学气相沉积法沉积具有n掺杂和本征非晶硅层堆叠的p型晶体硅衬底的特殊情况。前电极是通过溅射沉积的氧化铟锡层。准稳态光电导技术已被用来通过测量有效寿命和\ Dumplicit开路电压来表征发射器的质量。这些测量结果证实了沉积二氧化锡锡层后异质结的强烈降解。但是,还表明,通过适当的\超热处理可以完全恢复初始降解。从这个意义上讲,已经研究了在真空和烤箱内在100到160ºC的温度下10到90分钟的退火时间。

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